Bis trimethylsilyl acetylene safety data sheet print date. A12856 casno 1066542 synonyms no information available recommended use laboratory chemicals. Deprotection of trimethylsilyl group of an alkyne chemspider. Trimethylsilyl acetylene revision date 14feb2020 delayed and immediate effects as well as chronic effects from short and longterm exposure irritation no information available sensitization no information available carcinogenicity the table below indicates whether each agency has listed any ingredient as a carcinogen. Using this protected alkyne, as opposed to acetylene itself, prevents further coupling reactions and also has the benefit of being a liquid. Please see the following for information about the library and its accompanying search program. It is a colorless liquid that is soluble in organic solvents. Section 1 chemical product and company identification msds name. Acetylene cylinders are heavier than other cylinders because they are packed with a porous filler material and acetone. Safety data sheet creation date 12feb2015 revision date 14feb2020 revision number 2 1. Identification product name cyclopropyltrimethylsilylacetylene cat no. H53487 casno 81166849 synonyms no information available recommended use laboratory chemicals. The substance identity section is calculated from substance identification information from all echa databases. Chemeo is only indexing the data, follow the source links to retrieve the latest data.
Search results for trimethylsilylacetylene at sigmaaldrich. Silyl derivatives are widely used as protecting groups for various functions, mainly hydroxylated ones. Monoclonal antibody trial size samples click here for a free sample. Do not allow storage area temperature to exceed 50c. Get best price and read about company and get contact details and address. In the past 5 years, we have grown up as a famous fine chemicals supplier in china and we had established stable business relationships with samsung, lg, merck, thermo fisher scientific and so o. Ronald husk department of chemistry, university of wisconsin, madison, wisconsin 53706 u. Trimethylsilylacetylene1066542msds melting point boiling. Safety data sheet northwest missouri state university. Safety data sheet ghs product identifier other means of identification product type. Buy 11 naphthyl 2 trimethylsilylacetylene cas 104784512, a biochemical for proteomics research, from santa cruz. Suppliers list, emailrfq form, molecular structure, weight, formula, iupac, synonyms for trimethylsilyl acetylene cas no.
Rhodiumcatalyzed dimerization of triethylsilyl acetylene has been reported. Trimethylsilylacetylene, 98%, acros organics fisher scientific. Trimethylsilylacetylene, trimethylsilylacetylene supplier, trimethylsilylacetylene distributor, cas 1066542, trimethylsilylacetylene manufacturer, trimethylsilylacetylene wholesale. Low temperature raman study of bistrimethylsilylacetylene. However, we make no warranty of merchantability or any other warranty. In many instances introduction of the ethynyl group is facilitated by the use of tms acetylene. Called tms acetylene, it is used as a source of hc 2.
Triethylsilylacetylene, 97% c2h53sicch sigmaaldrich. Ethynyltrimethylsilane 98% trimethylsilylacetylene sigma. Acetylene may decompose explosively at elevated temperatures and pressures. Acetylene is dissolved in the acetone solution and dispersed throughout the porous medium.
This compound is used as a surrogate for acetylene. Safety data sheet creation date 16sep2014 revision date 25apr2019 revision number 4 1. Trimethylsilylacetylene is the acetylene hc2sich33. Keep container tightly closed and sealed until ready for use. Agno 3 and agotf proved to be the most effective catalyst in a mixture of methanol, water and dichloromethane. Safety data sheet external msds eu classification dsd outdated. Bistrimethylsilylacetylene substance information echa. Tristrimethylsilyloxyantimony sbosime33, 1 has been prepared from sbcl3 and 3 equiv. Our team of scientists has experience in all areas of research including life science, material science, chemical synthesis, chromatography, analytical and many others. If inhaled if breathed in, move person into fresh air. Btmsa is prepared by treating acetylene with butyl lithium followed by addition of chlorotrimethylsilane. Unexpected products from the reductive trimethylsilylation. Use of the information, documents and data from the echa website is subject to the terms and conditions of this legal notice, and subject to other binding limitations provided for under applicable law, the information, documents and data made available on the echa website may be reproduced, distributed andor used, totally or in part, for noncommercial purposes provided that echa is. Trimethylsilylacetylene is the acetylene hc 2 sich 3 3.
The source is also providing more information like the publication year, authors and more. Trimethylsilylacetylene 1066542 buy and find out price and availability, msds, properties of tcis high quality specialty chemicals. Bistrimethylsilylacetylene btmsa is an organosilicon compound with the formula c 2 sich 3 3 2. Ii prepared by safety and environmental affairs issue date sib1850. Avoid all possible sources of ignition spark or flame. Concentration information is not available for this spectrum and, therefore, molar absorptivity values cannot be derived. Show this safety data sheet to the doctor in attendance. Identification product name n,obis trimethylsilyl trifluoroacetamide, with 1% trimethylsilyl. Acids and bases have been used by chemists for centuries, and are among the most fundamental reagents employed in synthetic organic chemistry. Trimethylsilylacetylene 1066542 tci chemicals india pvt. Take the time to validate and double check the source of the data. In case of skin contact wash off with soap and plenty of water.
Trimethylsilyl azide, 96% safety data sheet sit8580. Cyclopropane,2trimethylsilylethynyl cas 81166849 msds msds. Acetylene is shipped in a cylinder packed with a porous mass material, and a liquid solvent, commonly acetone. Trimethylsilylacetylene supplier distributor cas 1066542.
Safety data sheet creation date 20nov2014 revision date 14mar2018 revision number 1 1. Structure, properties, spectra, suppliers and links for. Trimethylsilyl 2trimethylsilyloxypropanoate c9h22o3si2. Material safety data sheet n,obistrimethylsilylacetamide. Naphthalene,1 2trimethylsilylethynyl cas 104784512 msds 1. Trimethylsilyl acetylenes can be selectively deprotected in the presence of a catalytic amount of silver salts. Acetylene keep container in a cool, wellventilated area. According to mass spectrometric and nmr spectroscopic data, 1 appears to. Search results for trimethylsilyl acetylene at sigmaaldrich. Triethylsilyl acetylene, a bulky trialkylsilylprotected alkyne, undergoes cadiotchodkiewicz crosscoupling reaction with various bromoalkynes to yield synthetically useful unsymmetrical diynes. A chemoselective deprotection of trimethylsilyl acetylenes. All mass spectra in this site plus many more are available from the nistepanih mass spectral library.
Identification product name trimethylsilylacetylene cat no. Trimethylsilylacetylene is a versatile two carbon building block of considerable utility. Unlike acetylene itself, which is a gas at room temperature and potentially dangerous, this mono protected synthon is an easily handled liquid. Acetylene is an asphyxiant and presents a significant health hazard by displacing the oxygen in the atmosphere. Trimethylsilyl acetylene, tmsa, tms acetylen manufacturer supplier in china, offering trimethylsilyl acetylene intermediate for asymmetric synthesis, polyacrylic acid carbomercarbopol 940hc high clarity cas no. Chemicalbook provide chemical industry users with trimethylsilylacetylene boiling point melting point,trimethylsilylacetylene density msds formula use,if. Bistrimethylsilylacetylenehexafluoroacetylacetonato. Cyclopropyltrimethylsilylacetylene catalog numbers. Preexisting disorders involving any target organs mentioned in this msds as being at risk may be aggravated by overexposure to this product. Material safety data sheet product name airgas inc. Received july 7th, 1969 summary the reductive trimethylsilylation of. It is not to be considered as either a warranty or quality specification. Uses advised against not for food, drug, pesticide or biocidal product use details of the supplier of the safety data sheet emergency telephone number. Ethynyltrimethylsilane 98% trimethylsilylacetylene sigmaaldrich.
Cylinders should be stored upright, with valve protection cap in place, and firmly secured to prevent falling or being knocked over. Other functional groups, and especially silyl ethers, are not affected in these conditions. Identification product name cyclopropyltrimethylsilyl. Product name cyclopropyl trimethylsilyl acetylene cat no.
N,obistrimethylsilyltrifluoroacetamide, with 1% trimethylsilyl chloride revision date 25apr2019 precautionary statements prevention. Buy 4 trimethylsilyl ethynylmorpholine cas 64024631, a product for proteomics research applications, from santa cruz. Trimethylsilyl azide, 96% safety data sheet 05242016 en english us sds id. Tms acetylene, ethynyltrimethylsilane, trimethylsilylacetylene. The substance identifiers displayed in the infocard are the best available substance name, ec number, cas number andor the.
Uses advised against not for food, drug, pesticide or biocidal product use details of the supplier of the safety data sheet. Provide adequate fire protection during emergency response situations. The trimethylsilyl group protected can be desilyated with tbaf. Buy 4trimethylsilylethynylmorpholine cas 64024631, a product for proteomics research applications, from santa cruz.
Toxic fumes of hydrazoic acid will develop when material is exposed to water. A read is counted each time someone views a publication summary such as the title, abstract, and list of authors, clicks on a figure, or views or downloads the fulltext. Find more compounds similar to trimethylsilylacetylene. Bistrimethylsilylacetylene safety data sheet sib1850. China trimethylsilyl acetylene intermediate for asymmetric. When the valve of a charged acetylene cylinder is opened, the acetylene comes out of solution and passes out in the gaseous form. Uses advised against food, drug, pesticide or biocidal product use. Ethynyltrimethylsilane 98% trimethylsilylacetylene. Identification product name n,obistrimethylsilyltrifluoroacetamide, with 1% trimethylsilyl. Journal of organometallic chemistry elsevier sequoia sa, lausanne 65 printed in the netherlands unexpected products from the reductive trimethyl silylation of bistrimethylsilylacetylene laverne c. In many instances introduction of the ethynyl group is. Trimethylsilyl acetylene intermediate for asymmetric.
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